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Title: The Growth of a Crystal
Being the eighteenth Robert Boyle lecture
Author: Henry A. Miers
Release Date: May 10, 2015 [EBook #48914]
Language: English
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_The Growth of a Crystal_
BEING THE
EIGHTEENTH ROBERT BOYLE LECTURE
DELIVERED BEFORE
_THE OXFORD UNIVERSITY JUNIOR SCIENTIFIC CLUB_
_On the 20th of May, 1911_
BY
HENRY A. MIERS, M.A., D.SC. (OXON.), F.R.S.
PRINCIPAL OF LONDON UNIVERSITY
LONDON: HENRY FROWDE, AMEN CORNER, E.C.
EDINBURGH: 12 FREDERICK STREET. GLASGOW: 104 WEST GEORGE STREET
OXFORD: 116 HIGH STREET
NEW YORK: 29-35 WEST 32ND STREET
TORONTO: 25-27 RICHMOND STREET WEST
MELBOURNE: CATHEDRAL BUILDINGS, 205 FLINDERS LANE
1911
------------------------------------------------------------------------
OXFORD: HORACE HART
PRINTER TO THE UNIVERSITY
------------------------------------------------------------------------
THE GROWTH OF A CRYSTAL
When this date was fixed by your Secretary for the delivery of the BOYLE
Lecture, I discovered that it happened to be the fifteenth anniversary
of the very day on which I was first called upon to address a general
audience in Oxford. On May 20, 1896, I delivered an inaugural lecture as
Waynflete Professor of Mineralogy; when I look back upon the happy years
spent here in teaching and studying a science which is dear to me, I
feel that the present lecture should be an opportunity for expressing
gratitude for those peaceful years, not unmingled with regret that they
led to no such worthy achievement on my part as might have brought great
credit to the University and so have repaid something of the debt which
I owe to her.
Looking back from the busier world of London, it is easy to see how
ideal are the conditions under which an Oxford Professor conducts his
work; especially if his subject be one which does not overwhelm him with
students who pursue it only for the purpose of passing an examination.
Those who are attracted to his Laboratory probably come because they
have some natural taste for the subject; he finds it a pleasure to
devote his time to them; while his vacations and the conditions of
Oxford life give him unique opportunities for his own researches.
It is true that those who have most leisure not infrequently waste most
time. It is true also that the custom of Oxford is to burden her
students and scholars in addition to their teaching, with the conduct of
affairs which could be managed as well by persons specially appointed
for the purpose. Still it is also certain that to those who enter into
the genius of the place, and are animated by the spirit of Learning,
Oxford is prodigal of opportunity, and enables them to live the Academic
Life in a way which is scarcely possible elsewhere.
I know that the doors of the University are being opened to all the
newer studies, and that many a student spends most of his time in
acquiring the useful knowledge that is to equip him for his profession
and for the direct purpose of that profession; knowledge which is to fit
him to become lawyer, doctor, minister, engineer, or teacher; yet an
Oxford Professor may always maintain the pursuit of Learning for its own
sake and keep this purpose before his students even in their most
technical work.
Now Mineralogy is one of those sciences whose practical applications are
clear; it is necessary to the miner and the engineer; indeed, it sprang
from their needs; even Crystallography (that is, the study of Crystals),
which has always hitherto, though with little reason, been treated for
University purposes as a branch of Mineralogy, has also become part of
the necessary equipment of the practical chemist and geologist; but both
Sciences are, in their general aspects, very far removed from the
turmoil of practical life; it is with these aspects that I would fain
deal, and especially in relation to the study of crystals.
In this connexion, a passage which I quoted from GOETHE fifteen years
ago will bear repetition: ‘_There is a flavour_,’ he says, ‘_of the Monk
or of the old Bachelor about Crystallography and therefore it is
self-sufficient. Practical application in life it has none; its rarest
objects, the crystallized precious stones, have to be cut and polished
before we can adorn our ladies with them._’
In fact, this lecture, which I was constrained to prepare during a brief
holiday in Italy, was written in the midst of surroundings where it was
easier to think of Science as cultivated in the quiet of the Laboratory,
rather than in the restless scenes of its practical applications,
although I am familiar with both. Writing at a window overlooking the
mediaeval town and ancient walls of Perugia, with the view of peaceful
Assisi and the snowy cap of Monte Subasio across the plain, it was
easier to recall the hours of quiet toil and reflection spent in one’s
Laboratory at Oxford than visits to Mining Camp, or Metallurgical Works.
Accordingly when, under these circumstances, I set about choosing a
subject for the present occasion, it occurred to me that I might be
allowed to take up my discourse where I laid it down in 1896 and in some
sense to continue and conclude the remarks which I then made to the
University; and, considering how recently I have left you, I might
regard this as my farewell address corresponding to the opening lecture
which I then delivered.
In that address, I recollect, I began with an inquiry into the
resemblances and differences between minerals and other objects of
nature in respect of their beauty, especially as regards the beauty of
form which is so specially characteristic of minerals. Some minerals,
indeed, are found in delicate fronds and leaflets, and in mossy tufts,
which, in their form and texture, in their sheen and lustre, so closely
resemble plants that they are often mistaken for them. [Those who heard
RUSKIN’S lectures will remember the delight with which he described
these beauties of the mineral kingdom and the affection which he felt
for them.] I pointed out, I remember, that these delicate forms are,
like the frost patterns on a window-pane, really expressions of the
crystalline shape and symmetry of the mineral; each mineral consists of
crystals, and therefore has its own peculiar crystalline shape which is
one of its inherent properties; moreover, this persists unchanging
through the ages, and under all conditions, and is in no way dependent
upon the environment in which the mineral is situated.
The shape of a crystal does not depend like that of the animal or the
plant upon the life which its forefathers have led or the conditions
under which they have grown.
There are indeed other features in which a mineral or any crystal may
resemble a living thing in a way even more surprising than in its form.
Two of the most remarkable are these: it grows out of a solution as
though it were alive; and, if it is wounded or broken, it heals itself
and replaces the missing part just as a living organism may do. But, as
I pointed out, there is this radical difference. The crystal is not
responsive to the change of its surroundings; its form is not the result
of external forces; it does not adapt itself to its environment; it is
not undergoing any progressive evolution; but remains fixed and
unchanging. Its form is the expression of its permanent composition, and
so far as we know has always been the same. Indeed, until it has been
converted into its constituent elements and destroyed, it is in a sense
not only unchanging, but imperishable. For, take a crystal and break or
dissolve it away until only the tiniest fragment remains; that fragment
(e. g. sugar), though it may be only an invisible speck, will, if
immersed in the appropriate solution, continue to grow again and will
once more assume the form of a perfect crystal. Neither does it make any
difference if the crystal fragment has been kept for years or even
centuries; it will, when supplied with nourishment from the appropriate
solution, heal itself and continue to grow as though the process had
never been suspended. In a sense it is immortal, for, if not destroyed,
it never loses the mysterious power of growth, and is therefore more
imperishable than any seed or germ of life.
The main conclusion of my lecture was that, having been led by analogy
to compare the growing crystal with the growing plant, one finds the
growth and life of the crystal to be totally unlike the growth and life
of any organism. Its life is only an unchanging persistence without the
display of any struggle for existence, any movement, any adaptation, or
response to environment; its growth is only the addition of new material
on the surface of the old, without assimilation, so that the crystal
remains uniform and increases in size; there is no distinction of any
one part from any other; the crystal grows, therefore, without the
development of any organs.
One appears to be left with the conclusion that the crystal should be
regarded rather as a type of death than of immortality.
SCHOPENHAUER expressed this idea when he said: ‘_The crystal has only
one manifestation of life, crystallization, which afterwards has its
fully adequate and exhaustive expression in the rigid form—the corpse of
that momentary life._’
This, however, is not the conclusion which I would have you draw from
the facts; and I shall ask you on the present occasion to accompany me
in pursuing a little further the inquiry into what we may call the
vitality of a crystal and the manner in which it is displayed; although
this vitality is not to be confounded in any way with that of a living
plant or creature.
It is, I hope, not unfitting that the subject of crystal growth should
be dealt with in a BOYLE Lecture, for ROBERT BOYLE was himself one of
the first to treat it in a scientific spirit. He was the exact
contemporary of NICOLAS STENO, the famous Danish physician who laid the
foundation of modern crystallography; and BOYLE, in his treatise on the
origin and virtues of gems, was the first to express the conviction
which was almost simultaneously expressed by STENO—that gems must have
solidified from the liquid state. One of his reasons for thinking so was
their crystalline form, which resembles that of salts which crystallize
from solutions. Let me quote his exact words: ‘_The origin assigned to
gems may be countenanced by the external figuration of divers of them.
For we plainly see that the corpuscles of nitre, alum, vitriol, and even
common salt, being suffered to coagulate in the liquors they swam in
before, will convene into crystals of curious and determinate shapes._’
And then he points out that when a salt such as nitre crystallizes in a
vessel it is only where it is free to grow in the liquid, and away from
contact with the sides of the vessel, that it can acquire this shape.
These crystals (he says), ‘_having a fluid ambient to shoot in, will
have those parts of their bodies that are contiguous to the liquor
curiously formed into such prismatical shapes as are proper to nitre._’
When BOYLE wrote these words he had not seen the work of STENO, which
had just been published.
I may, therefore, claim that he was the first person to deal in a
scientific spirit with the subject which I have chosen for this lecture,
the ‘Growth of a Crystal.’
Three years before I came back to Oxford—on May 16th, 1893, the subject
of crystal structure had been treated in the second BOYLE Lecture in a
most original and masterly manner by no less a person than LORD KELVIN.
I well remember that Lecture, at which I had the good fortune to be
present; and to one who was already interested in crystals it was a
wonderfully illuminating and inspiring address.
On that occasion my venerable predecessor and teacher, Professor STORY
MASKELYNE, conducted LORD KELVIN to the lecture table.[1]
[Footnote 1: It is with the deepest regret that I add that my old friend
and revered teacher died on the very day on which these words were
spoken.—H. A. M.]
At that time, however, there was no laboratory in Oxford for
mineralogical and crystallographical research; the Professor only had a
lecture-room, he did not reside in Oxford, and his scientific work was
necessarily carried on elsewhere. To-day I am more fortunate in being
able to draw upon the resources of the well-equipped laboratory of my
successor, and former pupil, Professor BOWMAN, and upon his still more
valuable personal assistance and that of Mr. BARKER; so that, though I
only have to deal with ideas that are simple compared with those which
issued with fiery vigour from the fertile brain of the BOYLE Lecturer of
1893, I have a better opportunity of showing to an Oxford audience
to-day the actual things of which I am speaking, and may help to make my
meaning clear to those who cannot know much from personal experience
concerning the growth of crystals.[2] When I delivered my own inaugural
lecture I had no means of making visible to an audience the astonishing
features of crystal growth. Beautiful effects may easily be witnessed by
anyone with a few drops of common solution and a magnifying glass, yet I
believe that they are witnessed by comparatively few persons.
[Footnote 2: This lecture was beautifully illustrated by excellent
slides showing the actual _growth_ of crystals.—ED.]
I have alluded to laws of crystalline structure, to which LORD KELVIN
had directed attention: these are the laws of geometrical arrangement
which prove crystals to be constructed in an entirely different manner
from the living plants which they may so closely resemble; these laws,
however, were not established by observations or experiments upon the
growth of crystals. They were the result of a century of patient
measurements of the external shape of countless crystals; more than a
century of accurate determinations of what happens when heat and light
are transmitted through them and of numberless other experiments made by
physicists; and, added to this, the labours of mathematicians who
studied the manner in which solid particles could be arranged so as to
correspond to the geometrical and physical proportions thus determined
by experiment.
But all these were experiments and reasoning upon matter which appears
to be as nearly as possible inert; they entirely ignore the power of
growth possessed by crystals; indeed, no such power is contemplated by
the ordinary theories of crystal structure or could be predicted from
them.
So far, then, we may regard the comparison of crystals with plants and
all the fanciful ideas concerning their connexion with the origin of
life which were suggested by that comparison as only one more example of
the dangers of reasoning from analogy. The recollections that I retain
of the allusions to that process—in text-books of logic and treatises on
Science alike—give me the impression that examples of reasoning from
analogy are generally quoted only as instances of its danger and
futility. That, indeed, might seem to be the conclusion of my own
inaugural lecture; for, when we come to examine the growth and structure
of crystals, so far from finding that there is any real likeness to the
life and structure of the plants which they resemble, we find nothing
but a profound difference.
That, however, is not my real opinion, and was not my opinion fifteen
years ago. On the contrary, I have the greatest belief in analogy as one
of the most useful guides to discovery, and as the means by which in
practice new lines of investigation are most frequently opened and new
hypotheses suggested. In fact, I think that most of the advances which
are made in science, and especially in scientific theory, have been made
with the help of analogies.
If an explanation of any fact in Nature consists in correlating it with
some apparently distinct fact, and showing that the two have a common
cause, or are connected in a definite manner, how often has the
explanation of a new occurrence been suggested by the analogy of some
other known occurrence which is brought to mind by the memory; not by a
conscious effort of the reason, but by the recollection of a
resemblance. Do not some of the standard methods which are familiar in
the descriptions or criticisms of scientific discovery, such as
‘_reasoning from the known to the unknown_’, ‘_the adoption of a working
hypothesis_’, ‘_the scientific use of the imagination_’, often resolve
themselves on analysis into the simple process of being struck by an
analogy and being led by it to adopt an explanation or to try an
experiment suggested by it?
I daresay that scientific discoverers are ashamed to confess that they
may have been led to a theory by a superficial analogy just as they are
ashamed to confess that they have hit upon a discovery or an invention
by chance, and have found one thing when they were looking for another.
But there is no need to be ashamed, for the discoveries only come to
those who have the eyes to see, or the knowledge which enables them to
remember a resemblance, and who have further the intellectual power to
make use of it. Science grows on the acquisition of new knowledge and we
must not hesitate to grasp it where we can. There is a danger lest the
formulation of the methods of science may deter the inquisitive student
from seeking knowledge wherever it is to be found, and make him believe
that it is only by the orthodox processes of reasoning based upon a
lifetime of training that he is to discover anything new. Rather let him
be encouraged to seek any resemblance or analogy that may point a way in
the gloom.
It is true that in the past the argument from analogy has often proved
dangerous when, because the things possess certain attributes in common,
it was inferred that they are alike in other respects. Yet even here it
may prove useful. NEWTON only asserted that the diamond is inflammable
because it resembles other inflammable substances in possessing a high
refractive power; and yet he turned out to be right, although his
analogy was wrong. Moreover, it was the analogy which prompted the
experiment. To detect an analogy, to test it, and to find that it cannot
be maintained, may be as useful an addition to knowledge as the
establishment of a real causal relationship: it has had the effect of
setting the worker on to new experiments or observations, and every such
step is necessarily an advance. The conscientious search for one thing
almost invariably leads to the discovery of another; and, even if it
does not, who shall say that it may not be as important and useful, say,
to establish a difference as to prove the resemblance which has been
suspected?
If, however, reasoning from an analogy may be fallacious when inferences
are drawn from the fact that two things possess the same attributes in
common, it is, I think, a safer guide when it is used to suggest a new
hypothesis; a corpuscular theory of light may be suggested by the
analogy between the reflexion of light and the rebounding of elastic
bodies; an undulatory theory by the analogy of a wave propagated along a
string or on the surface of water. The one theory may be found to fit
the facts and the other may be condemned; but without some analogy as a
guide how are such theories to be devised? What we require in science
are continual stimuli to start us on new experiments, new observations,
and new ideas, and prevent us, especially those who are teachers, from
constantly repeating the old ones.
I shall be satisfied if the present lecture is regarded as a plea for
the use of reasoning from analogy, and as an illustration of its value.
Let me, then, after this exhortation, return to my problem of the growth
of crystals, and show how I still think that we may be guided by analogy
in seeking to understand it.
So far from regarding the growth of a crystal as of no further
importance after it has been proved to be quite different from the
growth of a plant, we must still think of it as one of the most
interesting and mysterious events, and the one through which we may hope
to get the clearest insight into the nature of the crystal itself.
For, after all, when after making physical experiments upon the solid
crystal and studying its action upon heat and light we are led to
speculate upon the manner in which it is constructed, we must not forget
that it grew, and that the material was laid down under conditions which
we can only understand by studying what happens on the surface as it
grows.
LORD CURZON devoted his ROMANES Lecture to the consideration of
Frontiers, and explained their interest and importance in the growth of
nations. In the study of Science also nothing is more interesting and
important than frontier problems. In two senses is this true. The
problems which lie on the borderland between two sciences are the most
fruitful of all, because they throw light upon each science, and, by
bringing into harmony things that were previously distinct and separate,
lead to an immediate extension of knowledge.
And also in a more restricted sense. You will find, I think, that the
scenes of the most interesting events in Nature are generally those
places where different things come into contact and where there is
consequently stir and action; where two substances meet to form a new
chemical compound; where two bodies touch and react upon each other; at
the surface of a solid or a liquid; these are the regions in which
events are taking place that we can study and measure with the prospect
of discovery.
Impressed by the analogy between the growth of crystals and of living
things, I have always felt that, for a proper understanding of the
things themselves, the study of their growth is as important for the one
as for the other; that to obtain this understanding it is necessary to
study what is happening on the surface of the growing crystal where the
advancing solid is in actual contact with the solidifying liquid. If you
wish to understand a plant or an animal it is not enough to study dried
specimens or specimens in spirits, but to watch the living organisms
growing under natural conditions; and in the same way it is surely worth
while to study the growing crystal surrounded by the solution which
feeds it, and even to make under these conditions the measurements and
observations which are usually made upon crystals only after they have
been taken out of the solution and have ceased to grow.
In the case of living things, we know that growth takes place by
internal processes and not only by new material added on the surface.
How much easier, then, should it be to study the growth of a crystal
when we have found that it is only a surface activity, and does not
involve internal changes?
As I have already said, when I came to Oxford there was no laboratory of
Mineralogy nor any apparatus for research, but I brought with me a piece
of apparatus which I had constructed a few years previously for this
exact purpose; to measure the angles of crystals while they are growing
in the solution and to ascertain whether any changes take place in those
angles, in the hope of getting some insight into the nature of the
surface and what I have called the frontier problem. Many days and also
nights had I spent with this apparatus in the absorbing pursuit of
measuring growing crystals, watching the curious changes that take place
in the position of their facets, excited by the knowledge that I was
looking at things that had certainly not been seen before, and by the
expectation of what they might disclose.
I need not weary this audience with any description of these
experiments, which doubtless seem more interesting and important to
their author than to anyone else. But I wish to draw your attention to
the result that came out of them. I found that it was possible with the
same apparatus to measure the refractive power of the liquid in absolute
contact with the growing crystal and from this to calculate the exact
strength of the solution at that spot. It was thus possible to prove
that the solution in contact with the crystal is rather stronger than at
a very short distance from it, and to know exactly how much stronger. In
other words, while a crystal of, say, alum is growing, the liquid in
contact with it contains more particles of alum and less particles of
water, or is richer in alum, than the liquid at a short distance from
it. I will ask you to bear this in mind in what follows. There is
another curious fact connected with this subject. Crystals of nitrate of
soda have almost exactly the same shape and almost the same physical
properties as crystals of the common mineral calcite, which, in its
purest and most perfect form of transparent glassy crystals, is known as
Iceland spar. Now, when a perfectly clean crystal of Iceland spar is
immersed in a strong solution of nitrate of soda, although it is not
dissolved by the liquid itself and therefore cannot crystallize out of
it, the Iceland spar actually continues to grow, and becomes enveloped
by the nitrate of soda so as to form what is apparently a single
crystal.
It appears, therefore, highly probable that a crystal of nitrate of soda
and a crystal of Iceland spar behave alike in this respect when placed
in a strong solution of the nitrate; each draws to itself the liquid
nitrate in the solution, then draws it out of the solution in the solid
state, and further arranges the particles upon its own surface in a
perfectly regular manner, so that the arrangement of the particles in
the shell of nitrate is the same as the arrangement of the particles in
the spar which it surrounds; just as a bricklayer sets upon the rising
wall new bricks arranged in the same way as those which he has already
laid. I remember that on LORD KELVIN’S last visit to Oxford, shortly
before his death, mindful of his BOYLE Lecture, I showed him, in company
with my pupil, Mr. BARKER, this beautiful experiment, with which he was
at that time not familiar, and I shall never forget the interest and
enthusiasm with which he witnessed the beautifully regular and
instantaneous growth of the nitrate crystals. He always was as
enthusiastic and inquiring as a boy, and these characteristics were
exhibited on that occasion in his old age. It is an experiment which
sets one thinking, and I have no doubt that, if LORD KELVIN, even at
that advanced age, had set his mind to consider it, he would have been
able to deduce far more than it has yet suggested to those who have
witnessed it.[3]
[Footnote 3: The experiment was then shown, exactly as it was shown to
Lord Kelvin.—ED.]
Some two years or so before the time of which I am speaking, Mr. BARKER
had at my suggestion made an exhaustive study of a great number of
different substances in order to ascertain which of them behave towards
one another like nitrate of soda and calcite, and why they do so, and he
has really discovered the secret. When two substances like nitrate of
soda and calcite have nearly the same shape and resemble one another
closely in their physical properties, the geometrical laws of
crystalline structure of which I have already spoken make it certain
that they consist of particles arranged in the same way. We do not know
what these particles are or what is their shape or size, but we may be
sure that they are arranged in the same way. I am perhaps using the word
particles in a loose sense, for they might be hollow cells or they might
be the space occupied by moving particles, or anything else, but
whatever they may be it is pretty certain that they are arranged in the
same way.
Well, Mr. BARKER has proved that, if two crystals grow together like
nitrate of soda and calcite, their particles are not only arranged in
the same way, but they must be of the same size, or at any rate occupy
the same space. In more scientific language, the two crystals not only
have the same molecular structure, but the same molecular volume. It is,
therefore, mainly a question of fitting together, and, if the two
structures do not fit, they cannot grow together, like nitrate of soda
and Iceland spar, as a continuous crystal.
Let me illustrate by a suggestive comparison. The bee’s cell is one of
the most remarkable and symmetrical structures in nature. Its regularity
is probably due to the fact that bees of the same size are, in making
it, so closely crowded together; there is one bee’s head in each cell,
and therefore you may say that the arrangement of the bees is the same
as that of the cells. For example, if you place in each cell a ball
which exactly fits it and then take away the cells, you have an
arrangement of balls which is the same as that of the cells, each being
in contact with six neighbours. It may be called a hexagonal
arrangement. You have only to push together a number of balls on a
table, and they will fall into this arrangement. It was a contemporary
and associate of BOYLE, and an Oxford man, Dr. ROBERT HOOKE, who pointed
out that with balls piled together in this way you can build up the
shapes of crystals, and that, for example, a pyramid of cannon-balls
stacked together in the manner that I have just shown, has the shape and
angles of an alum crystal. Now, if two such arrangements are to fit
together, they must be of the same size, whether they consist of bees,
or cells, or balls, or molecules. In the same way Mr. BARKER has proved
that Iceland spar and nitrate of soda must consist of materials which
are not only arranged in the same way, but are of the same size,
although we do not know in the least what that material is, nor what its
actual size may be.
But this, of course, is not the end of the whole mystery: for not only
do two such structures fit together, as might be expected, but each has
the remarkable property of making the other crystallize and grow, and
that means, as I have just explained, that it draws the other out of the
solution where it is liquid into the crystal where it becomes part of a
solid structure and lays it down in the exact position in which it fits,
just as one bee’s cell is added to another in the growth of the comb. We
have advanced a step, but only one step, towards the better
understanding of the mystery, and I would beg you to note how we are
continually led on by analogies which may be quite false, but which are
at any rate fruitful.
Now let me pass to another series of researches which were conducted by
Miss ISAAC and myself for a few years before I left Oxford and have
since been carried on by her with conspicuous success. Still
experimenting with the same apparatus, and endeavouring to trace how a
solution changes in strength while it is crystallizing, we came across
some curious and unexpected results. It is, of course, well known that
if a crystal, say of alum, is placed in a weak solution of alum it is
dissolved, and only has the effect of making the solution stronger, but
that at last a stage is reached at which the solution becomes
‘saturated’ and can dissolve no more, just as a stage is reached at
which a soaking sponge will hold no more water. At this point a crystal,
if put into it, remains unchanged. But it is quite easy to make the
solution still stronger, not by adding alum to it, but by taking water
away from it by evaporation: it then becomes oversaturated or
‘supersaturated’, and now a crystal of alum dipped into the liquid will
at once begin to grow and to make the solution weaker. In fact, this is
an unfailing test by which we can tell whether a solution is saturated
or supersaturated; and, more than this, until a bit of solid crystal
gets into it the liquid does not crystallize. Keep it in a closed vessel
so that no speck of alum can fall into it, and it will remain liquid for
weeks or years or as long as you please. But let the smallest possible
grain of an alum crystal fall into it, and crystallization will be
started; inoculate it with an invisible germ of alum dust, such as must
be flying about in the air of any room where dry alum is or has been
kept, and you will see the life and growth of a crystal begin when that
germ is introduced. This is the most extraordinarily sensitive test, and
one that can easily be applied.
In many of our experiments we found that during the first day when we
were working with some new substance it would not crystallize from an
exposed solution; but on the second day, when the air of the laboratory
had become impregnated with crystal germs, an exposed solution would
begin to crystallize at once.
Dr. TUTTON, one of the most accomplished investigators of crystals,
whose refined and beautiful researches were for many years carried on in
Oxford, has fully described these effects in his two books on crystals
just published, and confirms them from his own experience.
Now, Miss ISAAC and I have found in the course of our researches that,
as the solution becomes stronger and stronger—say, by the evaporation of
some of its water, it continues to be in the ordinary state of
supersaturation in which it does not crystallize save by inoculation
with a germ of solid alum crystal, but at last it suddenly reaches a
condition in which it can crystallize spontaneously, and at this moment
it is enough to stir or shake the solution, and you will at once witness
the birth of thousands of tiny crystals which appear as a cloud in the
liquid and begin to grow rapidly.
A very easy way in which to make this experiment is to dip a clean
needle into a drop of evaporating solution on a glass plate and to
scratch the glass on which the drop lies: for a time nothing happens,
and then suddenly, as the liquid passes into the new condition, a chain
of tiny crystals appears along the line of scratch.
That this suspended crystallization has a fixed limit was suspected, and
had been predicted by the German chemist OSTWALD, but could never be
proved until we made our experiments, and it was Mr. HARTLEY who first
helped us to interpret our results. He has subsequently, with his
pupils, made a number of investigations on the same subject.
I can show you the two conditions in one and the same drop by using a
solution of common potassium bichromate. Crystals begin to grow at the
edge of the drop where the liquid first becomes sufficiently strong, and
continue to grow slowly in the evaporating liquid which is only slightly
supersaturated. But in a few moments other parts of the drop which are
thinner become so strongly supersaturated that they begin to crystallize
spontaneously; and there you can witness the birth of new crystals which
grow rapidly in all directions, because they are growing in a solution
which is much stronger than that in which the first crystals are growing
slowly.
Does not all this set one thinking? What is taking place we cannot tell,
but we can only think of it as in some way analogous to the birth of a
cloud; and in both instances we have to picture to ourselves minute
invisible particles, of whose shape and size we know nothing, coming
together and coalescing till they grow into a drop or a crystal that we
can see. But why they do not begin to coalesce as soon as the liquid is
supersaturated it is difficult to say. We have to conceive the alum
solution as made up of moving particles of alum and of water, and it may
be that the particles are constantly coalescing into minute groups, but
as rapidly being broken up again, until a moment arrives at which the
alum particles are sufficiently dense to cohere permanently; but how
they attract one another and arrange themselves into the wonderful
structure which makes a crystal, of this we are entirely ignorant. The
question brings us back again to our initial mystery, how does the
crystal actually grow?
But this is not all. I have said that all solutions seem to behave in
the same way, and among them nitrate of soda, which we have already seen
growing in perfect regularity on Iceland spar. It appears, however, from
experiments made by Mr. BARKER, Miss ISAAC, M. CHEVALIER (who was
another of my pupils), and myself, that Iceland spar behaves in this
respect also exactly like nitrate of soda. In a solution which is
supersaturated, but is not strong enough to crystallize spontaneously,
not only will inoculation with a crystal of nitrate produce instant
crystallization; but inoculation with a crystal of Iceland spar produces
the same result. So we have a still more convincing proof of what I
suggested a short time ago, that two crystals, which have structures so
nearly identical that they can fit together, possess also the power of
drawing each other from the liquid state into the solid form of a
crystal. Whatever it is which conditions the fitting together of two
structures must then also confer upon them this extraordinary power of
making each other grow.
If I had more time, I should like to give an account of some of the more
important discoveries that have been made about crystals during the last
fifteen years, for they would make it easier to understand the present
state of our knowledge concerning them. I will only refer to two: one is
an experimental fact, and the other is a theoretical speculation, and
both are connected with the subject that I have been discussing.
It was discovered shortly before that time, and has been found by many
experiments since, that there are certain substances which are in a real
sense crystals, although they are liquid; that is to say, they affect
light in its passage through them just as solid crystals do.
These extraordinary substances, which had been investigated by Professor
LEHMANN, were first shown in England by Mr. BOWMAN and Mr. HARTLEY, who
were then working in my laboratory, at a conversazione at the Royal
Society, not long after their discovery, and I can well remember the
interest with which they were witnessed by Sir GEORGE STOKES and others.
We can only picture these liquids as consisting of particles which,
while they are free to move in all directions, always continue to face
the same way, like a group of dancers who in all their evolutions
continue to face the audience, instead of turning as they move. When the
mechanism which renders possible this remarkable behaviour is better
understood, we may be sure that it will bring about a better
understanding of the manner in which a solid crystal is constructed. The
interesting thing about it is that here at any rate the particles are in
violent movement instead of being comparatively stationary, as they are
in a solid crystal.
One is naturally led to imagine that before any solution begins to
crystallize in the solid form it passes into this liquid state, and that
the particles have begun to set themselves and all to face the same way
before they begin to cohere and to build themselves into a solid. But so
far as I know there is no evidence in favour of this suggestion—a
solution before solid crystals begin to appear does not behave like a
liquid crystal, but remains an ordinary solution up to the last moment
when new crystals are born in it or are started by inoculation with a
crystal germ.
The other discovery, which is in the nature of a speculation, is that of
another person whom I am proud to reckon among my former pupils, namely,
Professor POPE of Cambridge, working in conjunction with Mr. BARLOW. Mr.
BARLOW had already been referred to by LORD KELVIN in his BOYLE Lecture
as the author of ingenious researches upon the various ways in which
materials can be packed together, and the different arrangements and
structures which result from this packing.
These two workers have now propounded a theory according to which, if
the various atoms which constitute a substance are represented by
spheres whose sizes represent the valency of the atoms, and if these
spheres are packed together as closely as they will go, the resulting
structure will represent very nearly the structure of the crystal; and
so it may be possible for the first time from a knowledge of the
chemical constitution of a substance to predict the structure of its
crystals and therefore the form in which it will crystallize. You
remember the bee’s cell arrangement and the similar arrangement of balls
got by placing a ball in each cell and then removing the cells. Another
way of getting the same arrangement is to place a number of equal balls
on a table and to squeeze them together until they are packed as closely
as possible. This arrangement of closest packing, the arrangement of a
pyramid of cannon-balls, is precisely the same as before, the one in
which each ball on the table is in contact with six others. According to
POPE and BARLOW the atoms in a crystal simply pack themselves together
as closely as possible, but instead of being equal in size they have
generally to be represented as of different sizes according to their
valencies. If we imagine the coalescence of atoms to form a crystal to
be due to their mutual attraction, it is very reasonable to suppose that
they will get as close together as is possible, and therefore that the
ways of close packing are the ways of crystal structure. The theory
therefore suggests a reason for the growth as well as for the shape of a
crystal. I may remind you that the bee’s cell itself, which is in the
world of life the thing that most nearly resembles crystalline
structure, is due to this same principle of close packing; for in their
efforts to get as closely together as possible the bees are constrained
to get into the hexagonal arrangement. The bees crowd their heads
together and to each bee’s head corresponds one cell.
On the other hand, Professor SOLLAS has brought forward some most
suggestive and convincing speculations concerning certain crystals which
are based upon the principle of open, and not close, packing. His model
of silver iodide, for example, is well known in Oxford.
I have mentioned these recent contributions to science, not only with
the object of indicating that our knowledge of crystals is steadily
increasing, but also in order to point out that little has yet been done
to explain the mysteries of their growth. All that has been effected up
to the present is an attempt to explain how they are constructed, not
the process by which the construction takes place. It is as though we
were to analyse the form and structure of animals and plants and never
to watch them as they grow, but only to study them from fossils or from
museum specimens. And I believe the reason to be this. All the
speculations concerning crystals persist in regarding the particles of
which they consist as fixed and immovable: the theories are all
statical. And yet we know that the particles of matter, whatever they
may be, are really in lively movement. Is it not possible that in order
to get a correct understanding of the growth of a crystal we should take
account not only of the positions, but of the movements, of its
particles? Without some knowledge of these we are not able to approach
the problem, or to ascertain how a crystal either of nitrate of soda or
of Iceland spar draws the nitrate of soda out of the solution and makes
it grow into a solid.
Remember that when we say we know how the particles of a crystal are
arranged we really know nothing about their nature, and can only
represent them by spheres, or solid figures, or cells, or even points,
in order to get a representation of their arrangement. But we might
arrange in the same way a number of bodies each of which is whirling in
a fixed orbit, like a planet, about the corresponding point, or
vibrating about it like the prong of a tuning-fork, or pulsating like a
breathing animal; and so far from the arrangement being independent of
the movements it may be due to them.
If I may seek another analogy, let me take a group of figure skaters;
their centre remains fixed at the orange, maybe, about which their
figures are executed, but the group of skaters is at one moment extended
when they circle out to their furthest sweep, and at another moment
concentrated when they converge to the centre; and this alternating
expansion and compression occurs in a regular rhythm.
Imagine a pond covered by a number of such groups of skaters; the manner
in which they will fit in, and have to arrange themselves, will depend
both upon the dimensions and the rhythm of their curves, and they may
even interlace and become part of one great figure system covering the
whole pond. May not the growth of a crystal be something of this sort?
All the devices which I have quoted for picturing to ourselves the
architecture of a crystal I would regard as merely models representing
something that may be really quite different. But I venture to suggest
that the time has come when we should make use of moving and not
stationary models.
One need not go further than a spinning top for an illustration of
stability due to movement, and there is nothing unreasonable in the
suggestion that the rigidity of a crystal structure may be due to the
motion of its parts.
One curious observation which I have made is suggestive. I have many
times noticed that when the appropriate crystal is introduced into a
supersaturated solution, which is not strong enough to crystallize
spontaneously, it may cause crystals to grow not only in actual contact
with itself, but at some little distance in its neighbourhood. If this
be so, then the crystallizing force, the power of propagating crystal
growth, is not merely a frontier problem, but can be exercised through
the liquid to a distance. If I try to picture to myself what is
happening, I must again have recourse to analogy; I can only think of
the manner in which a string or a tuning-fork is set in vibration and
responds to a similar string or tuning-fork which is giving out its note
at the other end of the room; and so is it not possible that the
movements, whatever they are, vibrations or pulsations or regular
oscillations of some sort, which constitute crystalline growth may be
communicated through the almost crystallizing liquid, and culminate at
some point where they set similar material vibrating, that is to say,
crystallizing, in the same way?
I remember, when I first began to be interested in crystals in
undergraduate days, reading in _Nature_ an account of two papers which
seemed to have a possible bearing on the subject. One is an example of a
stationary arrangement of rigid bodies. The other illustrates the
principle which I am now suggesting, and is an arrangement of pulsating
bodies whose positions are due to their movements. The first was a
description of MAYER’S experiment on floating magnets which was, if I
remember right, shown here in a BOYLE Lecture by Sir JOSEPH THOMSON a
few years ago; an experiment in which magnets suspended in water by
corks and with their North poles projecting so that they repel one
another, are brought together by the attraction of a large magnet held,
with its South pole downwards, above the surface of the water; under the
joint influence of this attraction and their own mutual repulsions, they
group themselves into a number of interesting geometrical figures very
suggestive of the geometrical regularity of crystal structure. Indeed,
attempts have been made by LEHMANN to explain the architecture of a
crystal by a grouping of magnetic systems. And the other was the
experiment of BJERKNES in 1876 (described in _Nature_ in 1881), in which
a number of hollow elastic balls were made to expand and contract by
means of air tubes attached to them. These pulsating balls, when placed
in water, attracted and repelled one another like magnets, and arranged
themselves in a regular manner; thus suggesting that there may be many
unexpected ways in which rhythmical motion can exercise an attractive
and directive action such as is required to produce a crystal.
Let me illustrate what I mean by another crude analogy. Take a room full
of dancers; if they are all dancing to different times and in different
ways there will be no order or arrangement in the crowd, and it will
remain an incoherent jostling assembly of independent persons. But if
there are among them those who are moving to the same step and in the
same manner, and if they come together, they can become partners and can
continue to dance together; and if the room be filled with such dancers,
then the whole assembly can grow together into an orderly movement, and
only those whose step does not fit into the dance will be ejected and
left out. Or take another example: soldiers marching together have not
ceased to be individual men, but when they fell into step they became in
addition an organized body with a structure and a coherence that does
not belong to a miscellaneous crowd. Even so may the particles of
dissolved salt be endowed with a movement which enables them to enter
into partnership and cohere, and so to build themselves into the orderly
structure which makes up a crystal. And even so do crystals grow out of
a mixed solution as a pure and homogeneous substance and reject the
other materials which are dissolved in the liquid.
One other suggestion. If the growth of a crystal is really the coming
together of vibrating particles which cohere because they are in tune
with one another and so enter into a partnership like that of the
dancers or the figure skaters, then is it not possible that we may be
able to communicate these vibrations to a supersaturated solution, which
is so densely crowded that it is ready to crystallize, by some other
means than by inoculating it with the appropriate crystal? I think that
the time has come when we may be able to get some knowledge of the
manner of these movements by experimental methods; perhaps by studying
the sort of shock or movement, if there be any such, which starts
crystallization in a supersaturated solution; perhaps by finding other
substances, whose movements we understand, which are able to start the
crystallization when they are introduced into certain solutions.
I have said that the frontier problems in science are interesting; and
that this is true not only of the events that take place when different
bodies meet, but in another and more general sense. The most interesting
and fruitful problems are those which deal with the borderland between
two sciences, when the difficulties of the one are enlightened by the
experience of the other, or when the same problem is looked at from two
different sides. Let me only quote as an illustration the work connected
with osmosis, which attracted first the botanists and then the physical
chemists, and remind you of the enormous importance which it has assumed
by their combined efforts. I think it will be found that these problems
of crystal growth are of this borderland nature. And such problems can
only be satisfactorily attacked by those who are more than mere
specialists and can be led by the experience or the analogies of other
sciences.
I said that I should like to regard this lecture as an attempt to
justify the value of analogy. We poor specialists grope within the
confines of our own science, and what little advance we make is made in
part by the light we borrow from the other sciences. In these days of
increasing specialization what we need is to interest in our own
problems, not only those who are tilling the same fields with ourselves,
but even more, those who live on the other side of the fence which
surrounds us: to call to them across the frontier, to seek their advice
and assistance and the benefit of their experience.
This is one of the great advantages of a University, that workers and
thinkers in different subjects are brought together and can make their
difficulties known to each other. The connecting links between them are
the analogies which they perceive and which excite an interest that they
would not otherwise feel in each other’s work.
This is the reason why I have endeavoured to set before you a very
special problem in a very elementary way and as far as possible without
using technical terms. It is with the hope of attracting the interest of
workers in other subjects to this fascinating problem of crystal growth
which, from the time of BOYLE to that of RUSKIN, and more especially, as
I have shown you, in recent years, has engaged the attention of Oxford
students of crystals.
------------------------------------------------------------------------
Transcriber’s note:
Page 8, ‘allum’ changed to ‘alum,’ “corpuscles of nitre, alum, vitriol,”
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